Volume for blocked piping & Thermal RV

SOURCE
https://www.eng-tips.com/viewthread.cfm?qid=171158
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QUESTION

I am currently working on an LNG job and a question had come up as to the the minimum volume of blocked-in pipework (between 2 isolation valves) that require the addition of a Thermal PSV.
I have some very small inventories (of the order of 5 litres) on the LNG piping; the LNG will vaporise when blocked in - operating temp is about -165 Deg.C!!.
Does anyone have an idea when I should apply a TSV (inventory?), or should ALL sections on the piping system that can be blocked in have a TSV.

REPLIES

25362
To get an idea of the pressure developed on heating a packed liquid you may divide the absolute values of the cubic thermal expansion of the fluid

α = (1/ V)(∂ V/∂T)p

by its isothermal compressibility

κ = -(1/ V) (∂ V/∂ p)T

for the envisaged temperature range.

α and κ can be estimated from tables; α from the density changes, and κ from the sound speed in the liquid.

For additional reference:

http://webbook.nist.gov/cgi/fluid.cgi?Action=Load&ID=C74828&Type=SatP&;THigh=-120&TLow=-260&TInc=&RefState=DEF&TUnit=F&PUnit=psia&DUnit=lbm%2Fft3&HUnit=Btu%2Flbm&WUnit=ft%2Fs&;VisUnit=cP&STUnit=lb%2Fft